Dynamic processes involving the P4 cage coordinated to transition metal fragments were observed for the mononuclear complex trans-[Ru(dppm)2(H)(eta1-P4)]BF4 and for the bimetallic derivative trans-[Ru(dppm)2(H)(mu ,eta1:2-P4){Pt(PPh3)2}]BF4 as demonstrated by NMR experiments and DFT calculations.
Dynamic Behaviour of Ru and Ru-Pt complexes containing tetrahedron-P4 Ligand
Caporali Maria;Gonsalvi Luca;Ienco Andrea;Peruzzini Maurizio
2011
Abstract
Dynamic processes involving the P4 cage coordinated to transition metal fragments were observed for the mononuclear complex trans-[Ru(dppm)2(H)(eta1-P4)]BF4 and for the bimetallic derivative trans-[Ru(dppm)2(H)(mu ,eta1:2-P4){Pt(PPh3)2}]BF4 as demonstrated by NMR experiments and DFT calculations.File in questo prodotto:
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Descrizione: Dynamic Behaviour of Ru and Ru-Pt complexes containing tetrahedron-P4 Ligand
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