Regio- and stereoselective radical cyclizations of beta-substituted alpha-N-acetyl acrylamides have been performed. 6,5- and 7,5-fused bicyclic lactams were obtained, which can be viewed as conformationally restricted dipeptide mimetics.
Conformationally constrained dipeptides: Synthesis of bicyclic lactams by stereoselective radical cyclizations
Manzoni L;
1996
Abstract
Regio- and stereoselective radical cyclizations of beta-substituted alpha-N-acetyl acrylamides have been performed. 6,5- and 7,5-fused bicyclic lactams were obtained, which can be viewed as conformationally restricted dipeptide mimetics.File in questo prodotto:
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