Treatment of 2-diphenylphosphino-6-methylpyridine (dpPyMe) with Cu(CH3CN)(4)BF4 afforded the stable dinuclear Cu(I) complex [Cu-2(mu-dpPyMe)(3)(CH3CN)](BF4)(2). This compound is a weak emitter in solution, however a remarkably high emission quantum yield (46%) has been found in a rigid matrix at room temperature.
A stable and strongly luminescent dinuclear Cu(I) helical complex prepared from 2-diphenylphosphino-6-methylpyridine
Accorsi;Gianluca;Armaroli;Nicola;
2013
Abstract
Treatment of 2-diphenylphosphino-6-methylpyridine (dpPyMe) with Cu(CH3CN)(4)BF4 afforded the stable dinuclear Cu(I) complex [Cu-2(mu-dpPyMe)(3)(CH3CN)](BF4)(2). This compound is a weak emitter in solution, however a remarkably high emission quantum yield (46%) has been found in a rigid matrix at room temperature.File in questo prodotto:
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