In this article we report a detailed and understandable analysis of the evolution of various coherence orders in a Correlated 2D spectroscopy Revamped by Asymmetric Z-gradient Echo Detection (CRAZED) like pulse sequence, used to select a signal from intermolecular Multi Quantum Coherences (iMQCs). Because the signal tonoise-ratio of iMQC is much lower than the signal from conventional single quantum coherence (SQC), an optimization of experimental parameters is a necessity when measurements are made with iMQC. For this purpose a phase cycle is shown that not only allows a simpler selection of a particular quantum coherence order, but also removes receiver artifacts

About the crazed sequence

Capuani S.;
2004

Abstract

In this article we report a detailed and understandable analysis of the evolution of various coherence orders in a Correlated 2D spectroscopy Revamped by Asymmetric Z-gradient Echo Detection (CRAZED) like pulse sequence, used to select a signal from intermolecular Multi Quantum Coherences (iMQCs). Because the signal tonoise-ratio of iMQC is much lower than the signal from conventional single quantum coherence (SQC), an optimization of experimental parameters is a necessity when measurements are made with iMQC. For this purpose a phase cycle is shown that not only allows a simpler selection of a particular quantum coherence order, but also removes receiver artifacts
2004
INFM (attivo dal 18/11/1923 al 31/12/2021)
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/1103
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