We have developed a method to measure simultaneously the internal energy of bulk and the first layeratoms of a crystal. The internal energy of bulk and the surface atoms of lithium (110) have beenevaluated from 22 K up to above the melting transition, applying the Debye model to the thermalbroadening of the respective 1s photoemission lines. Our measurements clearly reveal two phasechanges: the known liquid to solid transition and the surface melting, occurring 50 K below the bulkmelting point.
Calorimetry at Surfaces Using High-Resolution Core-Level Photoemission
R. Larciprete;A. Baraldi;
2004
Abstract
We have developed a method to measure simultaneously the internal energy of bulk and the first layeratoms of a crystal. The internal energy of bulk and the surface atoms of lithium (110) have beenevaluated from 22 K up to above the melting transition, applying the Debye model to the thermalbroadening of the respective 1s photoemission lines. Our measurements clearly reveal two phasechanges: the known liquid to solid transition and the surface melting, occurring 50 K below the bulkmelting point.File in questo prodotto:
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Descrizione: Calorimetry at Surfaces Using High-Resolution Core-Level Photoemission
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