Some copper (II) cyanato complexes have been synthesised and characterised by elemental analysis, IR spectroscopy and X-ray photoelectron spectroscopy. Modified Auger parameters (alpha') have been evaluated and correlated with crystallographic and/or IR information on the coordination mode of cyanate to copper (II). The following trend has been found for alpha' values: high values (higher than 1850 eV) for bridging coordination mode and low values (lower than 1844 eV) for non-bridging structures.
X-Ray Photoelectron Spectroscopy insight into the Coordination modes of Cyanate in Copper(II) complexes
1991
Abstract
Some copper (II) cyanato complexes have been synthesised and characterised by elemental analysis, IR spectroscopy and X-ray photoelectron spectroscopy. Modified Auger parameters (alpha') have been evaluated and correlated with crystallographic and/or IR information on the coordination mode of cyanate to copper (II). The following trend has been found for alpha' values: high values (higher than 1850 eV) for bridging coordination mode and low values (lower than 1844 eV) for non-bridging structures.File in questo prodotto:
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