The investigated compounds were substituted naphtoquinones containing aniline moiety separated from the quinoid system by a methylene bridge. The nature of substituents on both donor and acceptor parts influenced the degree of formation of an internal charge transfer complex. Properties of the internal charge transfer interactions were investigated by voltammetry, spectroscopy, and in situ spectroelectrochemistry. Quantum chemical interpretation of experiments is given.
Electron Trasfer in Donor-Acceptor Molecules of Substituted Naphtoquinones: Spectral and Redox Properties of Internal
Fanelli N;Lanza C;Lampugnani L
1996
Abstract
The investigated compounds were substituted naphtoquinones containing aniline moiety separated from the quinoid system by a methylene bridge. The nature of substituents on both donor and acceptor parts influenced the degree of formation of an internal charge transfer complex. Properties of the internal charge transfer interactions were investigated by voltammetry, spectroscopy, and in situ spectroelectrochemistry. Quantum chemical interpretation of experiments is given.File in questo prodotto:
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MICROCHEMICAL JOURNAL 54, 478–486 (1996).pdf
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