Cyclohexanone monooxygenase catalyzes the asymmetric oxidazion of numerous alkyl aryl sulfides with the alkyl chain functionalyzed with Cl, CN, vinyl or hydroxy groups. Sulfoxides with enantiomeric excesses up to 99% were obtained. The structure of the sulfide markedly influenced enzyme enantioselectivity.
ASYMMETRIC OXIDATION OF SULFIDES BY CYCLOHEXANONE MONOOXYGENASE
SECUNDO F;CARREA G;
1993
Abstract
Cyclohexanone monooxygenase catalyzes the asymmetric oxidazion of numerous alkyl aryl sulfides with the alkyl chain functionalyzed with Cl, CN, vinyl or hydroxy groups. Sulfoxides with enantiomeric excesses up to 99% were obtained. The structure of the sulfide markedly influenced enzyme enantioselectivity.File in questo prodotto:
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