Various organouranium(IV) complexes of the general type Cp3UX (Cp =?5 -C5H5; X= Cl, CH3, n-C4H9 and C6H5) react in toluene solution with tetracyanoethylene and even with 7,7,8,8-tetracyanoquinodimethane to give new triscyclopentadienyluranium keteniminates. Their NIR-Vis spectra seem to be typical of U(IV) compounds with trigonal bipyramidal coordination around the metal.
Reactions of organouranium compounds with tetracyanoethylene and 7,7,8,8-tetracyanoquinodimethane
Rossetto;Brianese;Na;Ossola;Porchia;Ma;Zanella;
1987
Abstract
Various organouranium(IV) complexes of the general type Cp3UX (Cp =?5 -C5H5; X= Cl, CH3, n-C4H9 and C6H5) react in toluene solution with tetracyanoethylene and even with 7,7,8,8-tetracyanoquinodimethane to give new triscyclopentadienyluranium keteniminates. Their NIR-Vis spectra seem to be typical of U(IV) compounds with trigonal bipyramidal coordination around the metal.File in questo prodotto:
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Descrizione: Reactions of organouranium compounds with tetracyanoethylene and 7,7,8,8-tetracyanoquinodimethane
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