Binding of oxovanadium(IV) to ribonucleoside monophosphates, which involves initially the formation of VO(IV)-phosphate bonds and then the transfer of the metal ion to the deprotonated pair of 2'-3'-hydroxy groups, may also yield species which are stabilised by interaction of oxovanadium(IV) with phoshate and N(7) atom of the adenine moiety.
An EPR study on the binding of oxovanadium(IV) to nucleoside monophosphates. Evidence for the involvement of the purine moiety in the complexes of adenosine 5'-monophosphate.
E Alberico;D Sanna
1994
Abstract
Binding of oxovanadium(IV) to ribonucleoside monophosphates, which involves initially the formation of VO(IV)-phosphate bonds and then the transfer of the metal ion to the deprotonated pair of 2'-3'-hydroxy groups, may also yield species which are stabilised by interaction of oxovanadium(IV) with phoshate and N(7) atom of the adenine moiety.File in questo prodotto:
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