Chiral a-aminophosphane (a-P-C-N) ligands have been CH3O, CH3 or p-CH3OC6H4; Cl, C6H5), with complete prepared by reversible addition of Ph2PH to tri- diastereoselectivity. These complexes are stabilized in carbonylchromium benzaldimine complexes (CO)3Cr[eta 6-o- solution by electron-withdrawing group(s) on the imine. C6H4(Y)(CH=NR)] (with Y, R = CH3, CH3 or CH2COOCH3
Chiral a-P,N ligands from a diastereoselective Ph2PH addition to (eta 6-benzaldimine)tricarbonylchromium complexes
Baldoli Clara;
1999
Abstract
Chiral a-aminophosphane (a-P-C-N) ligands have been CH3O, CH3 or p-CH3OC6H4; Cl, C6H5), with complete prepared by reversible addition of Ph2PH to tri- diastereoselectivity. These complexes are stabilized in carbonylchromium benzaldimine complexes (CO)3Cr[eta 6-o- solution by electron-withdrawing group(s) on the imine. C6H4(Y)(CH=NR)] (with Y, R = CH3, CH3 or CH2COOCH3File in questo prodotto:
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Descrizione: Chiral a-P,N ligands from a diastereoselective Ph2PH addition to (h6-benzaldimine)tricarbonylchromium complexes
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