Reduction of dichloro-N,N?-ethylenebis(acetylacetoneiminato)molybdenum(IV), [Mo(acacen)Cl2], with sodium in the presence of diphenylacetylene afforded the diamagnetic dimer [Mo(acacen)]2 containing an Mo-Mo quadruple bond [Mo-Mo, 2.1678(4)Å], as shown by an X-ray crystal structure determination
A dimeric quadruply metal-metal bonded molybdenum(II)-Schiff's base complex: bis[N,N?-ethylenebis(acetylacetoneiminato)molybdenum(II)]
Giovanna Pennesi;
1988
Abstract
Reduction of dichloro-N,N?-ethylenebis(acetylacetoneiminato)molybdenum(IV), [Mo(acacen)Cl2], with sodium in the presence of diphenylacetylene afforded the diamagnetic dimer [Mo(acacen)]2 containing an Mo-Mo quadruple bond [Mo-Mo, 2.1678(4)Å], as shown by an X-ray crystal structure determinationFile in questo prodotto:
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