A Diode Laser Spectrometer for the In Situ Measurement of the HNO3 Content of Polar Stratospheric Clouds

A new instrument realized for measuring the HNO3 concentration in air is described. The device is a midinfraredabsorption spectrometer based on a tunable diode laser and a multipass absorption cell. The instrument isspecifically designed for airborne operation on board the M-55 Geophysica, in the frame of the Airborne PolarExperiment project, taking into account all the related environmental and operational constraints. The device ispart of a complete measurement package for the measurement of the chemical content of the polar stratosphericclouds and other atmospheric aerosols. Furthermore, it can be used as a stand-alone detector of molecular tracegases. The primary purpose of the instrument is to perform in situ diagnostic measurements in the uppertroposphere-lower stratosphere. Design criteria include a new optical setup, one much less sensitive to thevibration and thermal stresses with respect to the conventional diode laser spectrometers. Furthermore, theauthors developed a novel detection scheme for quicker acquisition and better signal-to-noise ratio. This paperreports calibration and testing measurements, including a detection lower limit both for the HNO3 and ammonia.This last gas is used as a wavelength and absorption reference.