An anisotropic nanopatterning method, based on a technique of atomic force microscopy (AFM) scribing of a thin polyimide film, is used to generate an alignment layer whose topography depends on the writing direction. Detailed experimental measurements are presented for the topographical anisotropy that arises when the polyimide alignment layer is scribed parallel and antiparallel to the AFM cantilever orientation. By means of a novel nanotomographic approach, the optical retardation delta of an alignable birefringent liquid that covers the scribed substrate is measured with unprecedented resolution of only a few tens of nanometers. In this technique a thin optical fiber is raster-scanned at several fixed heights inside the birefringent liquid, and the transmitted polarized light is collected downstream. The optical retardation delta from the fiber's tip to the polyimide interface was measured as a function of position x, y, z, with the results reflecting the spatially varying depth of the medium due to the polymer film surface topography. Theoretical calculations for delta are in excellent agreement with both the topographical and the high resolution nanoimaging experimental results obtained.

Nanoscale alignment and optical nanoimaging of a birefringent liquid

De Luca A;
2008

Abstract

An anisotropic nanopatterning method, based on a technique of atomic force microscopy (AFM) scribing of a thin polyimide film, is used to generate an alignment layer whose topography depends on the writing direction. Detailed experimental measurements are presented for the topographical anisotropy that arises when the polyimide alignment layer is scribed parallel and antiparallel to the AFM cantilever orientation. By means of a novel nanotomographic approach, the optical retardation delta of an alignable birefringent liquid that covers the scribed substrate is measured with unprecedented resolution of only a few tens of nanometers. In this technique a thin optical fiber is raster-scanned at several fixed heights inside the birefringent liquid, and the transmitted polarized light is collected downstream. The optical retardation delta from the fiber's tip to the polyimide interface was measured as a function of position x, y, z, with the results reflecting the spatially varying depth of the medium due to the polymer film surface topography. Theoretical calculations for delta are in excellent agreement with both the topographical and the high resolution nanoimaging experimental results obtained.
2008
INFM
SURFACE MODIFICATION
CRYSTAL ALIGNMENT
FORCE MICROSCOPY
POLYIMIDE
TRANSITION
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/124767
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
  • ???jsp.display-item.citation.isi??? ND
social impact