We have measured the almost-pure incoherent scattering function of liquid parahydrogen using neutron inelastic scattering. The experiment was carried out on TOSCA, atime-of-flight, inverse geometry, crystal analyser spectrometer, operating on the pulsed-neutron source ISIS (UK). Since the instrument kinematic region is close to a line in the (k,E)-plane, we have actually measured the projection of Sinc (k,?) on this line. The measured cross-section gives a direct experimental access to the microscopic dynamic of the centre-of-mass motion of molecular hydrogen. The data have been analysed using the Gaussian approximation and have been compared with the results of a novel Quantum Mechanical Molecular Dynamics simulation technique. The results are encouraging, but claim for further developments of the theoretical approach, as well as for more extensive experimental data.
Microscopic dynamics of liquid hydrogen
Zoppi M.;Colognesi D.;Celli M.
2001
Abstract
We have measured the almost-pure incoherent scattering function of liquid parahydrogen using neutron inelastic scattering. The experiment was carried out on TOSCA, atime-of-flight, inverse geometry, crystal analyser spectrometer, operating on the pulsed-neutron source ISIS (UK). Since the instrument kinematic region is close to a line in the (k,E)-plane, we have actually measured the projection of Sinc (k,?) on this line. The measured cross-section gives a direct experimental access to the microscopic dynamic of the centre-of-mass motion of molecular hydrogen. The data have been analysed using the Gaussian approximation and have been compared with the results of a novel Quantum Mechanical Molecular Dynamics simulation technique. The results are encouraging, but claim for further developments of the theoretical approach, as well as for more extensive experimental data.| File | Dimensione | Formato | |
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