Reduction-substitution reactions between high valent [ReOCl4][NBu4] or [ReNCl4][NBu4] complexes and the phenyldithiocarboxylate piperidinium salt lead to a novel rhenium(III) complex with mixed coordination sphere. The structure of this compound [Re(S3CPh)2(S2CPh)], containing two trithioperoxybenzoate and one dithiobenzoate ligands, has been elucidated by NMR, mass spectrometry and X-ray diffraction analysis.
Synthesis and characterization of the bis(trithioperoxybenzoate) (dithiobenzoate) rhenium( III) hetero complex
Tisato F;
1999
Abstract
Reduction-substitution reactions between high valent [ReOCl4][NBu4] or [ReNCl4][NBu4] complexes and the phenyldithiocarboxylate piperidinium salt lead to a novel rhenium(III) complex with mixed coordination sphere. The structure of this compound [Re(S3CPh)2(S2CPh)], containing two trithioperoxybenzoate and one dithiobenzoate ligands, has been elucidated by NMR, mass spectrometry and X-ray diffraction analysis.File in questo prodotto:
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Descrizione: Synthesis and characterization of the bis(trithioperoxybenzoate)(dithiobenzoate)rhenium(III) hetero complex
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