Bidentate 'PN' and tetradentate 'P2N2' ligands form stable silver(I) complexes, which were characterized by NMR and IR spectroscopy. Conductivity measurements indicate an ionic nature of the compounds in solution. A thorough mass spectrometric study (electrospray ionization and fast atom bombardment) of these complexes and the corresponding Cu(I) analogues supports the NMR and IR structural information.
Phosphinoamino complexes of copper(I) and silver (I): A combined NMR and IR spectroscopy, and electrospray ionization and fast atom bombardment mass spectrometry analysis
Crociani L;Traldi P;
1998
Abstract
Bidentate 'PN' and tetradentate 'P2N2' ligands form stable silver(I) complexes, which were characterized by NMR and IR spectroscopy. Conductivity measurements indicate an ionic nature of the compounds in solution. A thorough mass spectrometric study (electrospray ionization and fast atom bombardment) of these complexes and the corresponding Cu(I) analogues supports the NMR and IR structural information.File in questo prodotto:
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Descrizione: Phosphinoamino complexes of copper(I) and silver(I): a combined NMR and IR spectroscopy, and ESI and FAB mass spectrometry analysis
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