The ZnCl2-promoted cycloaddition of a series of enantiopure ortho-substituted benzaldehyde-Cr(CO)3 complexes and Danishefsky's diene gave the corresponding 2-aryl pyranones in good yields and complete enantiospecificity. Some of the mechanistic aspects of the cycloaddition were investigated and the reaction extended to different dienes
Stereoselective hetero Diels-Alder reactions of chiral tricarbonyl(eta-6-benzaldehyde)chromium complexes
Baldoli C;
2001
Abstract
The ZnCl2-promoted cycloaddition of a series of enantiopure ortho-substituted benzaldehyde-Cr(CO)3 complexes and Danishefsky's diene gave the corresponding 2-aryl pyranones in good yields and complete enantiospecificity. Some of the mechanistic aspects of the cycloaddition were investigated and the reaction extended to different dienesFile in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
prod_224395-doc_54272.pdf
accesso aperto
Descrizione: Stereoselective hetero Diels-Alder reactions of chiral tricarbonyl(eta-6-benzaldehyde)chromium complexes.
Dimensione
249.29 kB
Formato
Adobe PDF
|
249.29 kB | Adobe PDF | Visualizza/Apri |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
