Small angle neutron scattering (SANS) in low density 86Kr gas has been performed in order to measure the small- k behavior of the static structure factor S(k). Three number densities between 1.52 and 2.42nm-3 along the T = 297K isotherm have been studied. The small- k dependence of the Fourier transform c(k) of the direct correlation function c(r) has been derived. The experimental determination of the k3 term in the behavior of c(k) has led to a direct measurement of the London dispersion interaction in the pair potential of krypton. Also the contribution of the three-body potential in the asymptotic behavior of c(r) has been observed and related to the magnitude of the three-body interaction potential.
Long-range potential effects in low density krypton gas
F Formisano;U Bafile;
1997
Abstract
Small angle neutron scattering (SANS) in low density 86Kr gas has been performed in order to measure the small- k behavior of the static structure factor S(k). Three number densities between 1.52 and 2.42nm-3 along the T = 297K isotherm have been studied. The small- k dependence of the Fourier transform c(k) of the direct correlation function c(r) has been derived. The experimental determination of the k3 term in the behavior of c(k) has led to a direct measurement of the London dispersion interaction in the pair potential of krypton. Also the contribution of the three-body potential in the asymptotic behavior of c(r) has been observed and related to the magnitude of the three-body interaction potential.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
