The cationic complexes [Pd(?q3-allyl){Ph2P(o-C6H4NMe2)}]PF6 (1) and [PdMe(PPh3){Ph2P(o-C6H4NMe2)}]CF3SO3· C6H6 (2) catalyse, without any added phosphine, the telomerization reaction of 1,3-butadiene with methanol, showing high chemio- (> 95%) and regioselectivity towards the linear 1-methoxy-2,7-octadiene (> 93%).
Telomerization of butadiene with methanol catalysed by cationic palladium complexes containing a bidentate phosphinoamino ligand
Crociani L;
1999
Abstract
The cationic complexes [Pd(?q3-allyl){Ph2P(o-C6H4NMe2)}]PF6 (1) and [PdMe(PPh3){Ph2P(o-C6H4NMe2)}]CF3SO3· C6H6 (2) catalyse, without any added phosphine, the telomerization reaction of 1,3-butadiene with methanol, showing high chemio- (> 95%) and regioselectivity towards the linear 1-methoxy-2,7-octadiene (> 93%).File in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
prod_227657-doc_55970.pdf
solo utenti autorizzati
Descrizione: Telomerization of butadiene with methanol catalysed by cationic palladium complexes containing a bidentate phosphinoamino ligand
Dimensione
78.75 kB
Formato
Adobe PDF
|
78.75 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
