The Heck reaction of aryl dibromides and n-butyl acrylate catalyzed by Pd(OAc2/pO-Bu), is a high yielding method to produce intermediates for dihydroindacene type ligands. The same synthetic strategy, extended to tribromides, represents a simple route also to tridentate ligands potentially useful in the stabilization of trimeric metal complexes and clusters.
Facile route to dihydroindacene type ligands using multiple Heck reactions on aryl polybromides
Crociani L;Venzo A;
2002
Abstract
The Heck reaction of aryl dibromides and n-butyl acrylate catalyzed by Pd(OAc2/pO-Bu), is a high yielding method to produce intermediates for dihydroindacene type ligands. The same synthetic strategy, extended to tribromides, represents a simple route also to tridentate ligands potentially useful in the stabilization of trimeric metal complexes and clusters.File in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
prod_227745-doc_56004.pdf
solo utenti autorizzati
Descrizione: Facile route to dihydroindacene type ligands using multiple Heck reactions on aryl polybromides
Dimensione
881.83 kB
Formato
Adobe PDF
|
881.83 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
