Different silica-aluminas were shown to be effective catalysts for the opening of limonene oxide. Moreover, the two geometric isomers react at different rates to give different products; this allowed a kinetic resoln. Some silica-alumina cogels can also be used as supports for copper based catalysts, allowing the direct transformation of limonene oxide into carvenone.
Bifunctional copper catalysts. Part III. Carvenone synthesis starting from limonene oxide
Zaccheria F;Psaro R;
2001
Abstract
Different silica-aluminas were shown to be effective catalysts for the opening of limonene oxide. Moreover, the two geometric isomers react at different rates to give different products; this allowed a kinetic resoln. Some silica-alumina cogels can also be used as supports for copper based catalysts, allowing the direct transformation of limonene oxide into carvenone.File in questo prodotto:
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