New fluorobenzene chromium dicarbonylisocyanide complexes have been synthesized and evaluated in terms of their 'in solution' reactivity towards some nucleophiles. For the first time the polymer-bound isocyanides have been found to be valuable ligands for anchoring haloareneCr(CO)3 complexes by means of their substitution for a CO group. The supported fluorobenzene complex reacted with nitrogen-nucleophiles.
New polymer-bound haloarene chromium dicarbonyl isocyanide complexes: a successful study validating their use in chemistry
Baldoli Clara;
2000
Abstract
New fluorobenzene chromium dicarbonylisocyanide complexes have been synthesized and evaluated in terms of their 'in solution' reactivity towards some nucleophiles. For the first time the polymer-bound isocyanides have been found to be valuable ligands for anchoring haloareneCr(CO)3 complexes by means of their substitution for a CO group. The supported fluorobenzene complex reacted with nitrogen-nucleophiles.File in questo prodotto:
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Descrizione: New polymer-bound haloarene chromium dicarbonyl isocyanide complexes: a successful study validating their use in solid-phase chemistry
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