Complexation of the two pyridyl residues of a naphthalene imide guest by a V-shaped bis-porphyrinic host occurs with an association constant of the order of 10(8) M-1 and results in the quenching of the porphyrin luminescence with a rate of 1.2 x 10(10) s(-1), assigned to electron transfer.

Photoinduced electron transfer in a non-covalently linked donor-acceptor system: a bis-porphyrinic host and a naphthalene diimide guest

Lucia Flamigni;
2001

Abstract

Complexation of the two pyridyl residues of a naphthalene imide guest by a V-shaped bis-porphyrinic host occurs with an association constant of the order of 10(8) M-1 and results in the quenching of the porphyrin luminescence with a rate of 1.2 x 10(10) s(-1), assigned to electron transfer.
2001
Istituto per la Sintesi Organica e la Fotoreattivita' - ISOF
LIGHT-HARVESTING COMPLEX; 2 COORDINATION BONDS; NOBEL LECTURE; ASSEMBLIES; DYNAMICS; ENERGY; RECOGNITION; SPACER; STATE
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/154055
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