Chirality is rapidly induced in a fractal aggregate of the porphyrin t CuPagg by addition of a helical poly-glutamate. These results demonstrate a facile transfer of chirality via noncovalent interactions to preformed supramolecular assemblies grown in the absence of a chiral template.
Supramolecular chirality transfer to large random aggregates of porphyrins
Giovanna De Luca;Valentina Villari;Andrea Romeo;
2011
Abstract
Chirality is rapidly induced in a fractal aggregate of the porphyrin t CuPagg by addition of a helical poly-glutamate. These results demonstrate a facile transfer of chirality via noncovalent interactions to preformed supramolecular assemblies grown in the absence of a chiral template.File in questo prodotto:
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Descrizione: Supramolecular Chirality Transfer to Large Random Aggregates of Porphyrins
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