The Claisen-Schmidt reaction between 1,1'-diacetylferrocene and ferrocenecarboxaldehyde under microwave irradiation has been investigated in different conditions. The selective synthesis of 1,5-dioxo-3-ferrocenyl[5]ferrocenophane has been achieved and a simple protocol for its purification was established. The reaction was generally applicable to other non-enolizable aldehydes and the corresponding 1,5-dioxo-3-substituted [5]ferrocenophanes were obtained in high yield within 30 min.

Microwawe-assisted synthesis of 1,5-dioxo-3-substituted[5] ferrocenophanes

Pedotti S;Patti A
2008

Abstract

The Claisen-Schmidt reaction between 1,1'-diacetylferrocene and ferrocenecarboxaldehyde under microwave irradiation has been investigated in different conditions. The selective synthesis of 1,5-dioxo-3-ferrocenyl[5]ferrocenophane has been achieved and a simple protocol for its purification was established. The reaction was generally applicable to other non-enolizable aldehydes and the corresponding 1,5-dioxo-3-substituted [5]ferrocenophanes were obtained in high yield within 30 min.
2008
Istituto di Chimica Biomolecolare - ICB - Sede Pozzuoli
[5
Claisen-Schmidt condensation
Diacetylferrocene
Microwave-assisted synthesis.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/157303
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