The unusual structural features of syphonoside (1), recently reported from the marine mollusc Syphonota geographica and its prey Halophila stipulacea, stimulated further investigations on the minor secondary metabolites of both organisms. The three novel macrocyclic glycoterpenoids 2-4, structurally related to the main co-occurring metabolite 1, have been isolated and chemically characterized mainly by NMR spectroscopic technique, and degradation methods. Compounds 2 and 3 were found only in the rnollusc whereas compound 4 was isolated in trace quantities exclusively from the sea-grass. (c) 2007 Elsevier Ltd. All rights reserved.
Further syphonosides from the sea hare Syphonota geographica and the sea-grass Halophila stipulacea
Carbone Marianna;Mollo Ernesto;Cimino Guido
2008
Abstract
The unusual structural features of syphonoside (1), recently reported from the marine mollusc Syphonota geographica and its prey Halophila stipulacea, stimulated further investigations on the minor secondary metabolites of both organisms. The three novel macrocyclic glycoterpenoids 2-4, structurally related to the main co-occurring metabolite 1, have been isolated and chemically characterized mainly by NMR spectroscopic technique, and degradation methods. Compounds 2 and 3 were found only in the rnollusc whereas compound 4 was isolated in trace quantities exclusively from the sea-grass. (c) 2007 Elsevier Ltd. All rights reserved.File in questo prodotto:
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