We have measured hard x-ray photoemission spectra of pure vanadium sesquioxide (V2O3) across its metal-insulator transition. We show that, in the metallic phase, a clear correlation exists between the shakedown satellites observed in the vanadium 2p and 3p core-level spectra and the coherent peak measured at the Fermi level. Comparing experimental results and dynamical mean-field theory calculations, we estimate the Hubbard energy U in V2O3 (4.20 +/- 0.05 eV). From our bulk-sensitive photoemission spectra we infer the existence of a critical probing depth for investigating electronic properties in strongly correlated solids.

Coherent peaks and minimal probing depth in photoemission spectroscopy of Mott-Hubbard systems

Panaccione G;
2006

Abstract

We have measured hard x-ray photoemission spectra of pure vanadium sesquioxide (V2O3) across its metal-insulator transition. We show that, in the metallic phase, a clear correlation exists between the shakedown satellites observed in the vanadium 2p and 3p core-level spectra and the coherent peak measured at the Fermi level. Comparing experimental results and dynamical mean-field theory calculations, we estimate the Hubbard energy U in V2O3 (4.20 +/- 0.05 eV). From our bulk-sensitive photoemission spectra we infer the existence of a critical probing depth for investigating electronic properties in strongly correlated solids.
2006
INFM
METAL-INSULATOR TRANSITIONS
MEAN-FIELD THEORY
CR-DOPED V2O3
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/157408
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