The kinetics and energetics of the reversible reaction of phenols with the dpph? radical have been studied; steric shielding of the divalentNby the o-NO2 in dpph seems to be the main cause of the entropic barriers of this reaction.
Kinetic and thermodynamic parameters for the equilibrium reactions of phenols with the dpph radical.
Foti M C;
2006
Abstract
The kinetics and energetics of the reversible reaction of phenols with the dpph? radical have been studied; steric shielding of the divalentNby the o-NO2 in dpph seems to be the main cause of the entropic barriers of this reaction.File in questo prodotto:
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