Chiral homoallylic alcohols are easily accessible by asymmetric allylation of aldehydes with allyl trichlorosilane in the presence of catalytic amounts of a chiral tetradentate bis-sulfoxide, as organocatalyst, whose synthesis is reported.
A catalytic asymmetric allylation of aldehydes with allyl trichlorosilane activated by a chiral tetradentate bis-sulfoxide
Rosaria Villano;
2009
Abstract
Chiral homoallylic alcohols are easily accessible by asymmetric allylation of aldehydes with allyl trichlorosilane in the presence of catalytic amounts of a chiral tetradentate bis-sulfoxide, as organocatalyst, whose synthesis is reported.File in questo prodotto:
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