Coming together, breaking apart: A theoretical analysis of the oxidative coupling of two metal-coordinated disulfide species to a S42- rectangle provides an opening to a reexamination of a number of compounds hitherto considered to be disulfide complexes. An electronic framework helps explain how the nature of the metal controls inner redox processes and the alternative stabilization of S42- or 2 S22- (or S2-) species.
S-4(2-) Rings, Disulfides, and Sulfides in Transition-Metal Complexes: The Subtle Interplay of Oxidation and Structure Rings, Disulfides, and Sulfides in Transition-Metal Complexes: The Subtle Interplay of Oxidation and Structure
Mealli Carlo;Ienco Andrea;
2008
Abstract
Coming together, breaking apart: A theoretical analysis of the oxidative coupling of two metal-coordinated disulfide species to a S42- rectangle provides an opening to a reexamination of a number of compounds hitherto considered to be disulfide complexes. An electronic framework helps explain how the nature of the metal controls inner redox processes and the alternative stabilization of S42- or 2 S22- (or S2-) species.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
