The formation of novel complexes [M(dppm)(Ph2PCH2PPh2PPPP)]OTf (M = Rh, Ir, dppm = bisdiphenylphoshinomethane, OTf = OSO2CF3) bearing in their coordination sphere a new type of oligophosphorus ligands results from bimetallic activation and consequent transformation of white phosphorus. These complexesdisplay electrophilic properties and can be activated either electrochemically or by interaction with nucleophilic reagents.
Bimetallic Activation of White Phosphorus
Peruzzini Maurizio;Caporali Maria;Gonsalvi Luca;Midollini Stefano;
2008
Abstract
The formation of novel complexes [M(dppm)(Ph2PCH2PPh2PPPP)]OTf (M = Rh, Ir, dppm = bisdiphenylphoshinomethane, OTf = OSO2CF3) bearing in their coordination sphere a new type of oligophosphorus ligands results from bimetallic activation and consequent transformation of white phosphorus. These complexesdisplay electrophilic properties and can be activated either electrochemically or by interaction with nucleophilic reagents.File in questo prodotto:
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