Molecular dynamics simulations of the glass-forming liquid 2Ca(NO3)(2)center dot 3KNO(3) (CKN) were performed from high temperature liquid states down to low temperature glassy states at six different pressures from 10(-4) to 5.0 GPa. The temperature dependence of the structural relaxation time indicates that the fragility of liquid CKN changes with pressure. In line with recent proposal [Scopigno , Science 302, 849 (2003)], the change on liquid fragility is followed by a proportional change of the nonergodicity factor of the corresponding glass at low temperature. (c) 2008 American Institute of Physics.

Fragility and glassy dynamics of 2Ca(NO3)(2)center dot 3KNO(3) under pressure: Molecular dynamics simulations

Scopigno T;Ruocco G
2008

Abstract

Molecular dynamics simulations of the glass-forming liquid 2Ca(NO3)(2)center dot 3KNO(3) (CKN) were performed from high temperature liquid states down to low temperature glassy states at six different pressures from 10(-4) to 5.0 GPa. The temperature dependence of the structural relaxation time indicates that the fragility of liquid CKN changes with pressure. In line with recent proposal [Scopigno , Science 302, 849 (2003)], the change on liquid fragility is followed by a proportional change of the nonergodicity factor of the corresponding glass at low temperature. (c) 2008 American Institute of Physics.
2008
INFM
FORMING LIQUIDS
NITRATE MELTS
TRANSITION
RELAXATION
CA0.4K0.6(NO3)(1.4)
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/159064
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