Several remarkable dynamic properties of glass-forming materials have recently been discovered experimentally by the application of pressure. These properties have had a great impact on the research field of glass transition because they are general and fundamental, and not easy to explain. We review some of these experimental facts and show that they originate from the intermolecular interactions and many-body relaxation dynamics of the structural a-relaxation. While these properties are either not explained or not explainable by conventional theories and models, they can be rationalized by the coupling model.

Impact of the application of pressure on the fundamental understanding of glass transition

Capaccioli S
2008

Abstract

Several remarkable dynamic properties of glass-forming materials have recently been discovered experimentally by the application of pressure. These properties have had a great impact on the research field of glass transition because they are general and fundamental, and not easy to explain. We review some of these experimental facts and show that they originate from the intermolecular interactions and many-body relaxation dynamics of the structural a-relaxation. While these properties are either not explained or not explainable by conventional theories and models, they can be rationalized by the coupling model.
2008
INFM
GOLDSTEIN BETA-RELAXATION
SUPERCOOLED O-TERPHENYL
MISCIBLE POLYMER BLEND
FORMING LIQUIDS
ALPHA-RELAXATION
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/159091
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