A temperature-controlled metathesis/protonolysis takes place on group 4 amidopyridinate polymerization catalyst precursors. Unraveling this unprecedented reactivity path allowed us to highlight the importance of the metal precursor choice while preparing improved catalytic structures or studying new catalytic processes.
Intramolecular sigma-Bond Metathesis / Protonolysis on ZrIV and HfIV Pyridyl-Amido Olefin Polymerization Catalyst Precursors: Exploring Unexpected Reactivity Paths
Lapo Luconi;Giuliano Giambastiani;Andrea Rossin;Claudio Bianchini;
2010
Abstract
A temperature-controlled metathesis/protonolysis takes place on group 4 amidopyridinate polymerization catalyst precursors. Unraveling this unprecedented reactivity path allowed us to highlight the importance of the metal precursor choice while preparing improved catalytic structures or studying new catalytic processes.File in questo prodotto:
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