Batch reactors containing catalytic membranes based on molecular asymmetric hydrogenation catalysts immobilized onto hybrid PVA / inorganic polymers were engineered and tested in the enantioselective hydrogenation of prochiral substrates. All reactions were efficiently carried out in mild reaction conditions with ee's comparable to those of the corresponding homogeneous catalysts as well as minimal metal leaching upon reuse.
Enantioselective Hydrogenation of Prochiral Substrates in Catalytic Membrane Reactors
Barbaro Pierluigi;Bianchini Claudio;Liguori Francesca;
2011
Abstract
Batch reactors containing catalytic membranes based on molecular asymmetric hydrogenation catalysts immobilized onto hybrid PVA / inorganic polymers were engineered and tested in the enantioselective hydrogenation of prochiral substrates. All reactions were efficiently carried out in mild reaction conditions with ee's comparable to those of the corresponding homogeneous catalysts as well as minimal metal leaching upon reuse.File in questo prodotto:
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