The optical gas recognition capability of a covalently self-assembled monolayer of 5,10,15-tri-{p-dodecanoxyphenyl}-20-(p-hydroxyphenyl) porphyrin mols. on silica substrates was studied. The following analytes have been investigated: NO2, CO, CH4, H2, NH3, HCl, CHCl3, C2H5OH, CH3OH, pyridine, tetrahydrofurane, triethylamine, and DMF. The self-assembled porphyrin monolayer appears highly sensitive to 1 ppm of NO2 in both anhyd. and humid conditions. The selectivity of the self-assembled porphyrin monolayer with respect to other analytes was also examd. and present data show that the presence of CO, CH4, H2, and NH3 does not influence its UV-vis spectrum. Many common solvents slowly affect the position of the Soret band. The presence of HCl vapors results in a broad band extending over the entire 440-500 nm range while the starting Soret disappears. UV-vis measurements on a n-hexane 1.0×10-5 soln. of the 2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphine, that does not contain Ph substituents in the meso positions, show no changes in the optical spectrum upon NO2 interaction. It emerges that arom. substituents in the meso positions play a crucial role in detg. the optical sensing properties.
Characterization, Optical Recognition Behavior, Sensitivity, and Selectivity of Silica Surfaces Functionalized with a Porphyrin Monolayer
2005
Abstract
The optical gas recognition capability of a covalently self-assembled monolayer of 5,10,15-tri-{p-dodecanoxyphenyl}-20-(p-hydroxyphenyl) porphyrin mols. on silica substrates was studied. The following analytes have been investigated: NO2, CO, CH4, H2, NH3, HCl, CHCl3, C2H5OH, CH3OH, pyridine, tetrahydrofurane, triethylamine, and DMF. The self-assembled porphyrin monolayer appears highly sensitive to 1 ppm of NO2 in both anhyd. and humid conditions. The selectivity of the self-assembled porphyrin monolayer with respect to other analytes was also examd. and present data show that the presence of CO, CH4, H2, and NH3 does not influence its UV-vis spectrum. Many common solvents slowly affect the position of the Soret band. The presence of HCl vapors results in a broad band extending over the entire 440-500 nm range while the starting Soret disappears. UV-vis measurements on a n-hexane 1.0×10-5 soln. of the 2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphine, that does not contain Ph substituents in the meso positions, show no changes in the optical spectrum upon NO2 interaction. It emerges that arom. substituents in the meso positions play a crucial role in detg. the optical sensing properties.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
