Based on computer simulations of the primitive model of electrolytes, we show that the effective interaction between low-charge colloids in solvents of low or moderate dielectric constant depends crucially on the salt concentration. While in the absence of salt the interaction is repulsive in agreement with Derjaguin-Landau-Verwey-Overbeek theory, depletion of salt Bjerrum pairs around the colloids leads to an attraction between like-charge colloids even at small salt concentrations. Copyright (C) EPLA, 2007.

Interaction between charged colloids in a low dielectric constant solvent

E Zaccarelli;F Sciortino;
2007

Abstract

Based on computer simulations of the primitive model of electrolytes, we show that the effective interaction between low-charge colloids in solvents of low or moderate dielectric constant depends crucially on the salt concentration. While in the absence of salt the interaction is repulsive in agreement with Derjaguin-Landau-Verwey-Overbeek theory, depletion of salt Bjerrum pairs around the colloids leads to an attraction between like-charge colloids even at small salt concentrations. Copyright (C) EPLA, 2007.
2007
Istituto dei Sistemi Complessi - ISC
INFM
IONIC FLUIDS
ATTRACTION
MODEL
DEPLETION
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/159667
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