InMe, reacts with CNR (R=C6H4-p-OMe, C6H4-p-Me) affording the corresponding adducts Me3InCNR, which are formed even in the presence of an excess of CNR. Me3InCNR reacts with pyrrolidine to give the [Me2InC(=NR)(Pyrr)] products [Pyrr = conjugated base of pyrrolidine], which form through the insertion of CNR into the In-NPyrr, bond. These insertion products decompose easily to give the corresponding formamidines.

Reactions of InMe3 with isocyanides in the presence of amines: chemical and mass spectrometric evidence of unprecedented insertion into In-N bonds.

Crociani L;Rossetto G;Traldi P;Zanella P
2001

Abstract

InMe, reacts with CNR (R=C6H4-p-OMe, C6H4-p-Me) affording the corresponding adducts Me3InCNR, which are formed even in the presence of an excess of CNR. Me3InCNR reacts with pyrrolidine to give the [Me2InC(=NR)(Pyrr)] products [Pyrr = conjugated base of pyrrolidine], which form through the insertion of CNR into the In-NPyrr, bond. These insertion products decompose easily to give the corresponding formamidines.
2001
CHIMICA INORGANICA E DELLE SUPERFICI
Istituto di Chimica della Materia Condensata e di Tecnologie per l'Energia - ICMATE
Istituto di Scienze e Tecnologie Molecolari - ISTM - Sede Milano
isocyanides
pyrrolidine
formamidines
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Descrizione: Reactions of InMe3 with isocyanides in the presence of amines: chemical and mass spectrometric evidence of unprecedented insertion into In-N bonds.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/160480
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