The first organocatalytic Mukaiyama-Michael addition of 2-trimethylsilyloxy furan to nitroalkenes was promoted by Brønsted acids under solvent-free conditions. The conjugate addition took place in moderate to good yields with variously substituted nitroalkenes. The procedure is operationally simple and no workup is required.
Solvent-Free Organocatalytic Mukaiyama-Michael Addition of 2-Trimethylsilyloxy Furan to Nitroalkenes Catalyzed by Brønsted Acids
Rosaria Villano;
2009
Abstract
The first organocatalytic Mukaiyama-Michael addition of 2-trimethylsilyloxy furan to nitroalkenes was promoted by Brønsted acids under solvent-free conditions. The conjugate addition took place in moderate to good yields with variously substituted nitroalkenes. The procedure is operationally simple and no workup is required.File in questo prodotto:
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