Vibrational spectroscopies have been employed to study the fluorofullerenes of formula C60F18, C60F36, and C60F48. For the first time, the Raman spectra of C60F18, C60F36, and C60F48 as well as infrared (IR) spectra of their gaseous molecules isolated in cryogenic matrices have been obtained. The results were discussed and compared with the infrared spectra of the corresponding solids. In the case of C60F18, experimental data were supported by theoretical calculations.

Raman and infrared spectroscopic study of C60F18, C60F36 and C60F48.

JV Rau;
2004

Abstract

Vibrational spectroscopies have been employed to study the fluorofullerenes of formula C60F18, C60F36, and C60F48. For the first time, the Raman spectra of C60F18, C60F36, and C60F48 as well as infrared (IR) spectra of their gaseous molecules isolated in cryogenic matrices have been obtained. The results were discussed and compared with the infrared spectra of the corresponding solids. In the case of C60F18, experimental data were supported by theoretical calculations.
2004
Raman and FTIR spectroscopy
Matrix isolation
C60F18
C60F36
C60F48
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/16340
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