The chloro complexes are obtained in high yield (6390%) by reaction of [PtCl2(PhCN)2] with the proper thioether in 1/2 molar ratio, in anhydrous chloroform, at reflux under argon for ca. 10 h. The X-ray crystal structure of [PtCl2(MeS-o-C6H4Me)2 has been determined
Chloro and acetato complexes of platinum(II) with functionalized thioethers
Benetollo F
2005
Abstract
The chloro complexes are obtained in high yield (6390%) by reaction of [PtCl2(PhCN)2] with the proper thioether in 1/2 molar ratio, in anhydrous chloroform, at reflux under argon for ca. 10 h. The X-ray crystal structure of [PtCl2(MeS-o-C6H4Me)2 has been determinedFile in questo prodotto:
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