Reaction of [PdCl(h3-2-Me-allyl)(Ph2PPy)] (1) with AgBF4 affords the new dinuclear cationic complex [Pd(h3-2-Me-allyl)(m-Ph2PPy)]2(BF4)2 (2). The X-ray structural analysis of 2 shows that the 2-pyridyldiphenylphosphine ligands adopt a binucleating role through the P and N atoms bridging two independent palladium centres to form an eight-membered metallocyclic ring. One of the anti hydrogen atoms of the allyl moiety was located very close to a phenyl ring of Ph2PPy indicating the occurrence of a CH/p interaction. Addition of one equivalent of Ph2PPy to complex (2) affords the mononuclear cationic complex [Pd(h3-2-Me-allyl)(Ph2PPy)2](BF4) (3)
Cationic palladium(II)-allyl- complexes containing 2-pyridyldiphenylphosphine: X-ray crystal structure of the binuclear complex [Pd(eta3-2-Me-allyl)(mu-Ph2PPy)]2(BF4)2. Detection of an intramolecular C(allyl)-H...phenyl ring pi-interaction
F Benetollo;A Venzo;
2007
Abstract
Reaction of [PdCl(h3-2-Me-allyl)(Ph2PPy)] (1) with AgBF4 affords the new dinuclear cationic complex [Pd(h3-2-Me-allyl)(m-Ph2PPy)]2(BF4)2 (2). The X-ray structural analysis of 2 shows that the 2-pyridyldiphenylphosphine ligands adopt a binucleating role through the P and N atoms bridging two independent palladium centres to form an eight-membered metallocyclic ring. One of the anti hydrogen atoms of the allyl moiety was located very close to a phenyl ring of Ph2PPy indicating the occurrence of a CH/p interaction. Addition of one equivalent of Ph2PPy to complex (2) affords the mononuclear cationic complex [Pd(h3-2-Me-allyl)(Ph2PPy)2](BF4) (3)I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
