Neptunium is one of the few radioactive elements that are of great concern in the disposal of nuclear wastes in the geological repository, due to its hazards and the long half-life of the isotope, 237 Np (t1/2 = 2.14 × 106 years). To understand and predict the migration behavior of neptunium in the geological media, it is of importance to study its hydrolysis at elevated temperatures, because the temperature in the waste package and the vicinity of the repository could be high. Moreover, the chemical analogy between neptunium(V) and plutonium(V) adds even greater value to this investigation, because the latter could exist at tracer levels in neutral and slightly oxidizing waters but is difficult to study due to its rather labile redox behavior............
Hydrolysis of neptunium(V) at variable temperatures (10-85 degrees C)
Bismondo A
2004
Abstract
Neptunium is one of the few radioactive elements that are of great concern in the disposal of nuclear wastes in the geological repository, due to its hazards and the long half-life of the isotope, 237 Np (t1/2 = 2.14 × 106 years). To understand and predict the migration behavior of neptunium in the geological media, it is of importance to study its hydrolysis at elevated temperatures, because the temperature in the waste package and the vicinity of the repository could be high. Moreover, the chemical analogy between neptunium(V) and plutonium(V) adds even greater value to this investigation, because the latter could exist at tracer levels in neutral and slightly oxidizing waters but is difficult to study due to its rather labile redox behavior............I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
