The ring-closing olefin metathesis (RCM) of 2,2¢-divinylbiphenyls, using a second-generation RCM ruthenium-based catalyst, leads to differently substituted phenanthrenes in quantitative yield under very mild reaction conditions, independent of both nature and position of the groups present on the biphenyl moiety.
Ring-Closing Olefin Metathesis of 2,2'-Divinylbiphenyls: A Novel and General Approach to Phenanthrenes
Fabbri D
2004
Abstract
The ring-closing olefin metathesis (RCM) of 2,2¢-divinylbiphenyls, using a second-generation RCM ruthenium-based catalyst, leads to differently substituted phenanthrenes in quantitative yield under very mild reaction conditions, independent of both nature and position of the groups present on the biphenyl moiety.File in questo prodotto:
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