The article reports the first transition metal complex of methanesulfonylhydrazine, a molecule known for important pharmacological and chemical applications. The complex [ZnCl2(MSH)(2)], MSH = CH3SO2NHNH2, has been synthesized and its structure characterized by means of Xray analysis. The coordination geometry is pseudo-tetrahedral and the ligand MSH adopts a conformation that was found by previous ab initio calculations to be a transition state and not a stationary point for the free ligand.
Synthesis and Structure of the First Transition Metal Complex with Methanesulfonylhydrazine as a ligand
Ienco Andrea;Mealli Carlo;
2002
Abstract
The article reports the first transition metal complex of methanesulfonylhydrazine, a molecule known for important pharmacological and chemical applications. The complex [ZnCl2(MSH)(2)], MSH = CH3SO2NHNH2, has been synthesized and its structure characterized by means of Xray analysis. The coordination geometry is pseudo-tetrahedral and the ligand MSH adopts a conformation that was found by previous ab initio calculations to be a transition state and not a stationary point for the free ligand.File in questo prodotto:
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