According to the mosaic scenario, relaxation in supercooled liquids is ruled by two competing mechanisms: surface tension, opposing the creation of local excitations, and entropy, providing the drive to the configurational rearrangement of a given region. We test this scenario through numerical simulations well below the Mode Coupling temperature. For an equilibrated configuration, we freeze all the particles outside a sphere and study the thermodynamics of this sphere. The frozen environment acts as a pinning field. Measuring the overlap between the unpinned and pinned equilibrium configurations of the sphere, we can see whether it has switched to a different state. We do not find any clear evidence of the mosaic scenario. Rather, our results seem compatible with the existence of a single (liquid) state. However, we find evidence of a growing static correlation length, apparently unrelated to the mosaic one.

Mosaic multistate scenario versus one-state description of supercooled liquids

Cavagna, A;Grigera, TS;Verrocchio, P
2007

Abstract

According to the mosaic scenario, relaxation in supercooled liquids is ruled by two competing mechanisms: surface tension, opposing the creation of local excitations, and entropy, providing the drive to the configurational rearrangement of a given region. We test this scenario through numerical simulations well below the Mode Coupling temperature. For an equilibrated configuration, we freeze all the particles outside a sphere and study the thermodynamics of this sphere. The frozen environment acts as a pinning field. Measuring the overlap between the unpinned and pinned equilibrium configurations of the sphere, we can see whether it has switched to a different state. We do not find any clear evidence of the mosaic scenario. Rather, our results seem compatible with the existence of a single (liquid) state. However, we find evidence of a growing static correlation length, apparently unrelated to the mosaic one.
2007
Istituto dei Sistemi Complessi - ISC
INFM
GLASS-FORMING LIQUIDS
LENGTH SCALE
TRANSITION
HETEROGENEITY
DYNAMICS
File in questo prodotto:
File Dimensione Formato  
prod_1751-doc_30877.pdf

solo utenti autorizzati

Descrizione: Mosaic multistate scenario versus one-state description of supercooled liquids
Tipologia: Versione Editoriale (PDF)
Licenza: NON PUBBLICO - Accesso privato/ristretto
Dimensione 165.61 kB
Formato Adobe PDF
165.61 kB Adobe PDF   Visualizza/Apri   Richiedi una copia

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/167492
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 85
  • ???jsp.display-item.citation.isi??? ND
social impact