The electrochemical oxidation of 2,5-thienylene- (T) and 1,4-phenylene- (P) based arylene tetramers T4, TP2T and PT2P, in which the torsion angles between couples of adjacent rings are blocked by a chemical bridge, has been performed in acetonitrile. The products have been characterised by cyclic voltammetry, MALDI mass spectrometry, FT-IR, UV-vis and ESR spectroscopies, and in-situ conductivity and identified as radical cations, dimers or polymers depending on the T-P sequence in the monomer.
Polymers, dimers and radical cations from electrochemical oxidation of interring-bridged thiophene and thiophene-phenylene tetramers.
Destri S;Porzio W;Pasini M;
2001
Abstract
The electrochemical oxidation of 2,5-thienylene- (T) and 1,4-phenylene- (P) based arylene tetramers T4, TP2T and PT2P, in which the torsion angles between couples of adjacent rings are blocked by a chemical bridge, has been performed in acetonitrile. The products have been characterised by cyclic voltammetry, MALDI mass spectrometry, FT-IR, UV-vis and ESR spectroscopies, and in-situ conductivity and identified as radical cations, dimers or polymers depending on the T-P sequence in the monomer.File in questo prodotto:
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Descrizione: Polymers, dimers and radical cations from electrochemical oxidation of interring-bridged thiophene and thiophene-phenylene tetramers.
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