The new water soluble ruthenium complexes [(C5R5)RuCl(PTA)2] (R = H, Me; PTA = 1,3,5-triaza-7-phosphaadamantane) have been synthesised and applied to regioselective catalytic hydrogenation of unsaturated ketones in aqueous biphasic conditions and in studies of citotoxity towards selected tumor cell strains.
Synthesis, catalytic properties and biological activity of new water soluble ruthenium cyclopentadienyl PTA complexes [(C5R5)Ru(PTA)2Cl] (R = H, Me; PTA = 1,3,5-triaza-7-phosphaadamantane)
Gonsalvi Luca;Oberhauser Werner;Peruzzini Maurizio
;Vizza Francesco;
2003
Abstract
The new water soluble ruthenium complexes [(C5R5)RuCl(PTA)2] (R = H, Me; PTA = 1,3,5-triaza-7-phosphaadamantane) have been synthesised and applied to regioselective catalytic hydrogenation of unsaturated ketones in aqueous biphasic conditions and in studies of citotoxity towards selected tumor cell strains.File in questo prodotto:
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Descrizione: Synthesis, catalytic properties and biological activity of new water soluble ruthenium cyclopentadienyl PTA
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