The binuclear nickel(II) complex Ni2Cl4(cyclo-tetraphos) (cyclo-tetraphos = cis, trans, cis-1,2,3,4-tetrakis-(diphenylphosphino)cyclobutane) forms, upon activation with MAO, an effective and robust catalyst for the oligomerisation of ethylene to Schulz-Flory distributions of C4-C14 olefins with a mechanism where both chain transfer and chain propagation are first order in ethylene.
Schulz-Flory Oligomerisation of Ethylene by the Dinuclear Nickel(II) Complex Ni2Cl4[cis, trans, cis-tetrakis-(diphenylphosphino)cyclobutane]
Bianchini Claudio
;Gonsalvi Luca;Oberhauser Werner;
2003
Abstract
The binuclear nickel(II) complex Ni2Cl4(cyclo-tetraphos) (cyclo-tetraphos = cis, trans, cis-1,2,3,4-tetrakis-(diphenylphosphino)cyclobutane) forms, upon activation with MAO, an effective and robust catalyst for the oligomerisation of ethylene to Schulz-Flory distributions of C4-C14 olefins with a mechanism where both chain transfer and chain propagation are first order in ethylene.File in questo prodotto:
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Descrizione: Schulz-Flory Oligomerisation of Ethylene by the Dinuclear Nickel(II) Complex
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